Studies on fluorination of Fe3O4 (magnetite) by NH4HF2

نویسندگان

چکیده

Fluorination of magnetite (Fe3O4) by NH4HF2 was investigated using simultaneous thermogravimetry and differential thermal analysis (TG-DTA), observing the morphology phase changes scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM-EDS) diffractometry (XRD). The results indicate that fluorination involvement oxygen begins at room temperature, peaks 1784ºC, is completed 200ºC formation only (NH4)3FeF6. On heating, (NH4)3FeF6 gradually releases NH4F NH4FeF4 259ºC, then (NH4)0.l8FeF3 327ºC, finally FeF3 minor FeF2 400ºC due to partial reduction Fe (III) (II). At 550ºC, oxidized FeOF/Fe2O3.

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ژورنال

عنوان ژورنال: Journal of The South African Institute of Mining and Metallurgy

سال: 2023

ISSN: ['2411-9717', '0038-223X']

DOI: https://doi.org/10.17159/2411-9717/1639/2022